logistically $\pm a$ means "either $a$ or $-a$" and $\mp a$ means "either $-a$ or $a$". Logistically they are exactly the same.
However $\mp a$ looks unnatural and lopsided so by convention we always use $\pm a$.
So if we ever do see $\mp a$ there usually is some other reason; that elsewhere in the expression there is an indication that whether we chose $a$ or $-a$ is dependant on something else. For instance: If I saw: $k = a \pm \sqrt {b \mp c}$, I would interpret it as there being two cases: Either $k = a + \sqrt{b - c}$ or that $k = a - \sqrt{b + c}$.
But this is unavoidably ambiguous. I would also inconsistantly interpret a statment $k = a \pm \sqrt{b \pm c}$ as having four possible cases: $k = a + \sqrt{b + c}; k = a -\sqrt{b+c}; k = a +\sqrt{b-c}; k = a-\sqrt{b-c}$.
Care should be given to avoid potential ambiguity.