For categories $\mathcal{C}$ and $\mathcal{D}$, a pair of functors $\mathcal{C} \xrightarrow{\;R\;} \mathcal{D}$ and $\mathcal{C} \xleftarrow{\;L\;} \mathcal{D}\,$ are an adjoint pair if for any objects $X$ of $\mathcal{C}$ and $Y$ of $\mathcal{D}$ we have a bijection
$$ \operatorname{Hom}_\mathcal{C}(LY,X) \;\simeq\; \operatorname{Hom}_\mathcal{D}(Y,RX) \,. $$
Recently, I've come across an exercise* asking to prove that a pair of functors are an adjoint pair, and then additionally to prove that
$$ \operatorname{Ext}^1_\mathcal{C}(X,LY) \;\simeq\; \operatorname{Ext}^1_\mathcal{D}(RX,Y) \,. $$
What is the significance of this adjoint-like relationship with $\operatorname{Ext}$ instead of $\operatorname{Hom}$? The exercise I'm looking at didn't provide any motivation for proving this.
* In the exercise, $X$ and $Y$ are categories of quiver representations, and $R$ and $L$ are reflection functors across a sink and source vertex respectively. This category is hereditary, so $\operatorname{Ext}^i$ vanish for $i > 1$.