I will expand on i-m-soloveichik's comment, because it really answers the question. In Solution of Polynomials by Real Radicals (Amer. Math. Monthly 92 (1985), 571-575), Isaacs prove the following theorem.
Theorem. If $x \in \overline {\mathbb Q}$ is an algebraic number having the following properties:
- $x$ is totally real: it is real, and so are all of its conjugates [in other words: its minimal polynomial splits over $\mathbb R$];
- $x$ is a real radical element: it lies in a field $F_r \subset \mathbb R$ at the top of a tower of extensions
$$F_0 = \mathbb Q \subset F_1 \subset F_2 \subset \ldots \subset F_r$$
such that forall $j$, $F_j/F_{j-1}$ is an extension generated by an element $\alpha_j$ which has a power in $F_{j-1}$. [In other words, $x$ is expressible in termes of real-valued radicals];
Then $x$ is constructible.
I find this theorem truly remarkable: if I allow you to take all the real $n$th roots that you want, you couldn't construct a single totally real number more than the kid down the block with just his square root.
Obviously, the situation is better for non totally real numbers, starting with $\sqrt[n]{2}$ and the like, but it makes you reconsider the definition of solvable by radicals, does it not?
For the second part of your question, it suffices to remark that $\kappa_n = \cos(2 \pi/n)$ is a totally real number. (Note that $\mathbb Q(\kappa_n)$ is a Galois extension of $\mathbb Q$, because it is a subextension of the $n$th cyclotomic field, whose Galois group is abelian, so every conjugate of $\kappa_n$ must lie in $\mathbb Q(\kappa_n) \subset \mathbb R$).
As such, one can apply your theorem to $\kappa_n$, which will be "expressible in terms of real-valued radicals" if and only if it is constructible, that is, if and only if the regular $n$-gon is straightedge-and-compass-constructible. It's famously not the case for $n = 7$.
(One easily transfers the result from $\kappa_n = \cos(i 2 \pi/n)$ to $\sigma_n = \sin(i 2 \pi/n)$, since the relation $\kappa_n^2 + \sigma_n^2 = 1$ means that one is constructible (resp. expressible in termes of real radicals) if and only if the other is).