Recall that if $f$ is irreducible over a field $F$, then $F[x]/\langle f \rangle \cong F(\alpha)$, where $\alpha$ is any root of the polynomial. Since $b^2 - 4ac < 0$ for this polynomial $ax^2 + bx + c$ in $\mathbb{R}[x]$, its roots are imaginary, and the polynomial is irreducible over $\mathbb{R}$. From this, we have $\mathbb{R}[x]/\langle ax^2 + bx + c \rangle \cong \mathbb{R}(\alpha)$, where $\alpha$ is one of its roots.
Thus, the problem boils down to showing that $\mathbb{R}(\alpha) \cong \mathbb{C}$, where $\alpha = a + bi$ with $a, b \in \mathbb{R}$ and $b \neq 0$. By definition, $\mathbb{R}(\alpha) = \{f(\alpha) \ | \ f \in \mathbb{R}[x]\}$, from which it is clear that, at least, $\mathbb{R}(\alpha) \subseteq \mathbb{C}$. To show that these fields are actually equal, we want to demonstrate that we can produce any given complex number by finding a polynomial in $\mathbb{R}[x]$ and evaluating it at $\alpha$. I'll leave it to you to explicitly write down a (linear) polynomial that outputs the generic complex number $c + di$ when evaluated at $\alpha$.