If $\arctan(2)$ were a rational multiple of $\pi$, then $\alpha=\frac{1+2i}{\sqrt{5}}$ would be an $m$-th root of unity for some $m\in\mathbb{N}$. On the other hand, the minimal polynomial of $\alpha$ over $\mathbb{Q}$ is $x^4+\frac{6}{5}x^2+1$, and this is not a cyclotomic polynomial since cyclotomic polynomials always have integer coefficients (by Mobius inversion formula, if you like). It follows that $\alpha$ is not an $m$-th root of unity and
$$ \frac{\arctan 2}{\pi}\color{red}{\not\in}\mathbb{Q}.$$
Small variation: there are not so many cyclotomic polynomials with degree $4$. As many as the solutions of $\varphi(n)=4$, given by $n\in\{8,10,12\}$. The minimal polynomial of $\alpha$ does not belong to the set $\{\Phi_8(x),\Phi_{10}(x),\Phi_{12}(x)\}$ and the conclusion is the same.
Anyways, by the Shafer-Fink inequality a pretty good approximation of $\arctan 2$ is provided by
$$ \frac{\pi}{2}-\frac{3/2}{1+2\sqrt{1+1/4}}=\color{blue}{\frac{1}{8} \left(3-3 \sqrt{5}+4 \pi \right)}.$$