Here's a way to understand it using essentially only one fact: the integral of the product of an even function ($f(x)=f(-x)$) and an odd function ($f(x)=-f(-x)$) is zero:
If $f$ is even and $g$ is odd, then
$$ \int_{-\infty}^{\infty} f(x)g(x) \, dx = 0. $$
Any function $f$ can be written as the sum of an even function and an odd function:
$$ f(x) = \frac{f(x)+f(-x)}{2} + \frac{f(x)-f(-x)}{2}. $$
Call the former fraction $f_e$, the latter $f_o$.
How does the Fourier transform work on the even and odd part? We can split $e^{ikx}=\cos{kx}+i\sin{kx}$, and the cosine is even, the sine odd. Therefore, if we write $F(k) = \int_{-\infty}^{\infty} e^{ikx} f(x) \, dx$,
$$ F(k) = \int_{-\infty}^{\infty} (\cos{kx}+i\sin{kx})(f_e(x)+f_o(x)) \, dx \\
= \int_{-\infty}^{\infty} (\cos{kx}) f_e(x) \, dx +i\int_{-\infty}^{\infty} (\sin{kx}) f_o(x) \, dx, $$
since the other integrals vanish. But both these integrands are even, so they are equal to twice the integral over $(0,\infty)$:
$$ F(k) = 2\int_{0}^{\infty} (\cos{kx}) f_e(x) \, dx +2i\int_{0}^{\infty} (\sin{kx}) f_o(x) \, dx = F_c(k) + iF_o(k), $$
say. But the evenness of cosine means that $F_c$ is even, and in the same way $F_o$ is odd. Moreover, both are obviously real. But then, considering the right-hand side of Parseval,
$$ \int_{-\infty}^{\infty} F(k) G(k)^* \, dk = \int_{-\infty}^{\infty} (F_c(k)+F_s(k)) (G_c(k)-G_s(k)) \, dk = \int_{-\infty}^{\infty} F_c(k) G_c(k) \, dk + \int_{-\infty}^{\infty} F_s(k) G_s(k) \, dk; $$
the other two terms vanish because $F_c,G_c$ are even and $F_s,F_s$ are odd.