The space $W^{1,\infty}(\Omega)$ is usually defined as all functions $v \in L^\infty(\Omega)$ with weak derivatives of first order and these derivatives shall belong to $L^\infty(\Omega)$.
Then, you can define $W_0^{1,\infty}(\Omega) := H_0^1(\Omega) \cap W^{1,\infty}(\Omega)$, i.e., all functions in $W^{1,\infty}(\Omega)$ whose trace is zero.
Note that $C_c^\infty(\Omega)$ is not dense in $W^{1,\infty}(\Omega)$. In fact, if $\{v_n\}\subset C_c^\infty(\Omega)$ converges towards $v$ in $W^{1,\infty}(\Omega)$, the (continuous) derivatives of $\{v_n\}$ converge uniformly towards the derivatives of $v$. Hence, $v$ has continuous derivatives. But not all functions in $W^{1,\infty}(\Omega)$ possess continuous derivatives.