It's well known that a connected Riemannian manifold induces a metric space: the distance between two points ia measured as the infimum of the length of curves joining the points. The inverse: given a metric space, there is a connected Riemannian manifold that induces it?
I post it as a curiosity. All what I know is the metric space would be a path metric space, so, for example, it has to be locally path connected.