Let $A$ be a smooth commutative $k$-algebra, for $k$ a commutative ring. By the Hochschild–Kostant–Rosenberg theorem, we have that $\mathrm{HH}^*_k(A) \cong \bigwedge^* \mathrm{Der}_k(A, A)$, where $\mathrm{Der}_k(A,A)$ is the $A$-module of $k$-linear $A$ derivations. Recall that $\mathrm{HH}^*_k(A)$ is an graded-commutative algebra under cup product (it is actually a Gerstenhaber algebra, but we only need the cup product for now).
If $k$ is a field with characteristic not 2, it is easy to see that the relation $[f] \smallsmile [f] = 0$ for $[f] \in \mathrm{HH}^1_k(A)$ is satisfied, as $[f] \smallsmile [f]$ is 2-torsion. On the other hand, some more work seems to be required in the characteristic $2$: even given $A = \mathbb{F}_2[x, y]$, it is not immediately obvious to me (and perhaps I just haven’t played around with this enough) how to decompose $[\frac{\partial}{\partial x}]\smallsmile[\frac{\partial}{\partial x}]$ as a sum of Hochschild $2$-boundaries, i.e., functions of the form $f(a, b) = a \cdot g(b) - g(ab) + g(a) \cdot b$. Does anyone know such a decomposition?