The following is an example taken from Dummit and Foote.
Let $F$ be a field of characteristic $\neq 2$ and let $K$ be an extension of $F$ of degree 2, $[ K : F]=2$. Let $\alpha \in K$ not contained in $F$. Then $\alpha$ satisfies an equation of degree at most $2$ over $F$. It follows that the minimal polynomial of $\alpha$ is the monic quadratic, $$m_{\alpha}(x)=x^2 + bx +c$$ Since $F \subset F(\alpha) \subseteq K$ and $K$ and $F(\alpha)$ have the same degree we have that $F(\alpha) = K$. The roots of the quadratic extension can be determined by the quadratic formula, $$\alpha = \frac{-b \pm \sqrt{b^2 - 4c} }{2}$$ Here $b^2 - 4c$ is not a square in $F$ because $\alpha$ in not an element of $F$.
Why does $\alpha \notin F$ imply the discriminant is not a square ?
Now $F(\alpha) = F \left ( \sqrt{b^2 - 4c} \right)$ as follows: by the formula above, $\alpha$ is an element of the field $F \left ( \sqrt{b^2 - 4c} \right)$
How does the quadratic formula give us this information? I'm assuming $F \left ( \sqrt{b^2 - 4c} \right)$ looks something like this, $b_0+b_1 \left ( \sqrt{b^2 - 4c} \right)$. Then $\alpha$ is in this field extension if we know that $\pm \frac{b}{2} \in F$. How do we know this is true?