The middle thirds Cantor Set doesn't work since at stage $N$ there are $2^N$ intervals of length $\frac{1}{3^N}$. So for some $\epsilon$ the Hausdorff dimension of this Cantor set, the series is more than $0$:
$$ \left(\frac{2}{3^{\epsilon }}\right)^N =1 \longrightarrow \epsilon = \frac{\log 2}{\log 3} $$
It is also the limit set of the two functions $T_1(x) = \frac{x}{3}$ and $T_2(x) = \frac{x}{3} + \frac{2}{3}$.
If we remove successively smaller percentages, we can get Cantor sets of positive Lebesgue measure. The Smith-Volterra-Cantor set is nowhere-dense and has Lebesgue measure $\frac{1}{2}$.
These disasters come up when you try to show $\int_a^b f'(x) \, dx = f(b) - f(a)$ for certain trig series.
Considering this is like the Putnam exam, let's try to take "aggressive" Cantor sets. Instead of removing the middle $\frac{1}{3}$ at each stage, let's remove the middle $1-\frac{1}{N}$. Now after stage $N$ there are $2^N$ sets, but these have measure:
$$ 2^N \cdot \left(\frac{1}{N!}\right)^\epsilon \approx \left(\frac{2 e^\epsilon}{N}\right)^N \to 0$$
and this is true for all $\epsilon$. Using iterated functions we are using $T_{1,N}(x) = \frac{x}{N}$ and $T_{2,N}(x) = \frac{x}{N} + (1-\frac{1}{N})$. Here are some notes on dimension theory.
Here a lot of work has gone into constructing nice sets, but we need two nice sets $X,Y\subset [0,1]$ with $X + Y = [0,2]$. Necessarily $0,1 \in X \cap Y$.
It is certainly true that $C + C = [0,2]$ I don't think this is true for the set I have constructed.
Another route might be to try building "Cantor sets" using continued fractions whose digits are bounded or avoid a certain number.
$$ A_k = \{ [a_1, \dots, a_k, \dots] : 0 \leq a_i < k \} \subset \mathbb{Q} $$
These sets may be sparse enough and have the sum property you desire.