In essence, I am looking for an example of a semigroup or a semicategory (closure is not that important, but it is useful) that is NOT a monoid or category.
Hopefully, there is a neat and simple-to-understand example of an only-associative operation on an infinite set.
Edit: Also, non-commutative!
Edit #2: From all the answers, it seems there are no associative, non-identity, non-inverse operations on the reals such that for $x,y \in \mathbb{R}$ the operation is $x \cdot y = f(x,y)$ where $f(x,y)$ is a some analytically expressible function, such that the reals form a semi-group under that operation.