D.W. has shown how to solve the problem in a general setting. Let me show the simplest way for this particular problem.
What is $S^*$?
$S^*=\{w\in\{a,b\}^*: w\text{ does not contain }bb\text{ and }w \text{ does not start with } b\}$.
The description above can be shown, for example, by demonstrating that the right hand side contains $\epsilon, a, aa, ab$ and its concatenation with itself.
Recurrence relation
Let $f_n$ be the number of words of length $n$ in $S^*$. Then $f_0=1$ and $f_1=1$.
Let $w$ be a word of length $n+1$, $n\ge1$.
- $w$ ends with $a$. Then $w=xa$ for $x\in S^*$ of length $n$.
- Otherwise, $w$ ends with $b$. Then $w=yab$ for $y\in S^*$ of length $n-1$.
The above shows that $f_{n+1}=f_n+f_{n-1}$. So $f_n$ is the famous Fibonacci sequence.
Final formula
$$f_n=\frac{\left(\dfrac{1+\sqrt5}2\right)^n-\left(\dfrac{1-\sqrt5}2\right)^n}{\sqrt5}$$
Exercise. (One minute or less if you find the shortcut.) How many distinct words of length $n$ appear in $\{a,bb\}^*$?