PLA can be annealed (some formulations better than others), increasing the heat deflection temperature up to (depending on the specific material and whose test results you believe and how much force it needs to withstand at high temperature) somewhere between 90 °C and 140 °C. Variants sold as "high temperature" PLA ("HTPLA") tend to be more suitable to annealing and give better results. "High speed" PLA (including Creality's "Hyper PLA") will be the worst for this. Look for products based on Natureworks Ingeo 3D870 resin. Very few vendors document what base resin they use, but some do. I'm familiar with Fusion Filaments who does offer it.
Other options would be PET, PETG, ABS, or ASA, but these cannot be printed well (some of them not at all) on an original Ender 3 with PTFE-lined hotend, which can't be safely operated over around 245 °C. If your Ender has an all-metal hotend though you could print them. These materials are good to somewhere between 75 °C and 100 °C.
If you do not need extreme rigidity, TPU, normally thought of as flexible, can be very rigid if you use a 95A or even better 98A hardness variant, and print with high or 100% infill, as long as the part geometry itself isn't thin. TPU is good to over 100 °C without deforming.