Here, $\mathbb{S}^n$ is a vector space, and we're asked to check that the subset $\mathbb{S}^n_+ \subset \mathbb{S}^n$ has some special properties:
(1) $\mathbb{S}^n_+$ is a cone, that is, for every $\textbf{X} \in \mathbb{S}^n_+ - \{\mathbf{0}\}$, the entire ray with vertex $\bf 0$ passing through $\bf X$ is also contained in $\mathbb{S}^n_+$. Algebraically, any matrix in this ray can be written as $\lambda \bf X$ for some $\lambda \geq 0$.
(2) $\mathbb{S}^n_+$ is convex, that is, for semidefinite matrices $\textbf{A}, \textbf{B} \in \mathbb{S}^n_+$, the line segment in $\mathbb{S}^n$ with endpoints $\textbf{A}, \textbf{B}$ is contained in $\mathbb{S}^n_+$. Algebraically, any matrix on this line segment can be written as a convex combination of $\bf A$ and $\bf B$, that is, as $t \textbf{A} + (1 - t) \textbf{B}$ for some $t \in [0, 1]$.
We can show readily that $\mathbb{S}^n_+$ has both of these properties by appealing to the definition of positive semidefinite matrix, namely that a given matrix $\bf X$ satisfies
$${}^t \textbf{zXz} \geq 0$$ for all $\mathbf{z} \in \mathbb{R}^n$.