The existence of positive eigenvalue having an eigenvector with all positive entries for this case guaranteed by the application of Perron Frobenius theorem.
Perron Frobenius theorem: If all entries of a $ n \times n $ matrix $A$ are positive, then it has a unique maximal eigenvalue. Its eigenvector has positive entries.
Though this can't be directly applicable, in this case one assumes the matrix is irreducible, that is, from any page, we can go to any other page via a sequence of pages. Another way of saying this is that the graph must be connected. If this happens, then there will be a power of the matrix which will have all entries positive. So, PF theory is applicable to this power of $ A$ which in turn will imply the result on $A$.
By the way, this is connected with Markov chain theory in probability except that you have to take the transpose of the matrix to get the transition matrix of the Markov chain. Then general theory of Markov chain will imply that there is stationary distribution (the version of the eigenvector) under the same assumption of connected graph. In fact there is a fairly simple expression for the eigenvector for the undirected graph.