We can recursively construct the parenthesis structure using strong induction.
We know that for two arguments, there is exactly one possible grouping--this is the base case. As we add an argument, we can construct the different ways we can group. Lets call the number of groups for $n$ arguments as $G_n$ (so we know that $G_2 = 1$, $G_3 = 2$, $G_4 = 5$, $G_5 = 14$--at the least)
\begin{align*}
\left(a_1...a_{n - 1}\right) + a_n && \text{$G_{n - 1}$} \\
\left(a_1...a_{n - 2}\right) + \left(a_{n - 1} + a_n\right) && G_{n - 2}G_2 \\
\left(a_1...a_{n - 3}\right) + \left(a_{n - 2} + a_{n - 1} + a_n\right) && G_{n - 3}G_3
\end{align*}
You probably see a pattern here: $G_n = \sum\limits_1^{n - 1}G_iG_{n - i}$ (where we assume $G_1 = 1$). So we see:
\begin{align*}
&G_3 = G_1G_2 + G_2G_1 = 1 + 1 &= 2 \\
&G_4 = G_1G_3 + G_2G_2 + G_3G_1 = 2 + 1 + 2 &= 5 \\
&G_5 = G_1G_4 + G_2G_3 + G_3G_2 + G_4G_1 = 5 + 2 + 2 + 5 &= 14 \\
&G_6 = G_1G_5 + G_2G_4 + G_3G_3 + G_4G_2 + G_5G_1 = 14 + 5 + 4 + 5 + 14 &= 42
\end{align*}
This looks very similar to the binomial expansion so I would expect there to be a combinatorial solution.