The relation $\mathcal{R}=\{(1,2),(2,3)\}$ (note, this is the relation $\mathcal{R}$, not "$x\mathcal{R}y$" which is a statement not the relation as a whole) is not transitive because for it to have been transitive we would have required that for every possible choice of $x,y,z$ (possibly repeating), if we had $x\mathcal{R}y$ and $y\mathcal{R}z$ that we would also have needed $x\mathcal{R}z$.
Since $(1,2)\in\mathcal{R}$ and $(2,3)\in\mathcal{R}$ but $(1,3)\not\in\mathcal{R}$ the relation is not transitive.
"The relation doesn't state that 1 does not correspond to 3 as well." On the contrary, the relation is very specifically defined to include those things listed in it and only those things listed in it. Since $(1,3)$ is not listed in the definition of $\mathcal{R}$, that directly confirms that $1$ is not related to $3$.