Your idea is perfect. The monotone convergence theorem guarantees convergence of a sequence if you can show that the sequence is increasing and bounded above (or decreasing and bounded below). To get that your sequence is increasing, the trick is to use strong induction:
The base case is easy, so I'll leave that to you. Next, suppose that each subsequent term is larger than the previous for each of the first $k$ terms. We want to show $s_{k+1} > s_k$, and because we used strong induction, we can assume $s_{k} > s_{k-1}$, which gives the inequality $s_{k+1} = \sqrt{2 + \sqrt{s_k}} > \sqrt{2+\sqrt{s_{k-1}}}$. And what is $\sqrt{2 + \sqrt{s_{k-1}}} \ $?
This argument is implicitly using the fact that $\sqrt{\cdot}$ is an increasing function, but this is fairly easy to prove.
If you wanted to actually find the limit of the sequence, first note that $\{s_{n+1} \}$ is a subsequence of $\{s_n\}$. If $ \{s_n \}$ converges, any subsequence also converges to the same value. Taking a limit of both sides of that equality, we get:
$$\lim(s_{n+1}) = \lim \left( \sqrt{2 + \sqrt{s_n}} \right)$$
Applying limit laws, and recognizing that $\sqrt{\cdot}$ is a continuous function$^\dagger$, we'll have:
$$\lim(s_{n+1}) = \sqrt{ 2 + \sqrt{ \lim(s_n)}}$$
We know $\{s_n\}$ converges to some $L \in \mathbb{R}^+$ and $\{s_{n+1} \}$ to the same, so the above reduces to:
$$L = \sqrt{2 + \sqrt{L}}$$
Solving for $L$, we find that it is a root of the quartic $L^4 - 4L^2 - L + 4$. Notice that $1$ is a root, so we can factor out $(L-1)$, reducing the problem to finding roots of the cubic $L^3 + L^2 - 3L - 4$. You can find its three roots using the cubic formula (two of them will have nonzero imaginary part, so our $L$ will be the single real root). The cubic formula is a mess, so you can also arrive at an arbitrarily good approximation for $L$ using Newton's method. Either way, we get $L \approx 1.8312$.
$^\dagger$We're applying the fact that, if $f$ is a continuous function and $\{a_n\}$ a convergent sequence in the domain of $f$, then $a_n \to M \implies f(a_n) \to f(M)$.