It is a well-known result in homotopy theory that a fibration $F \rightarrow E \rightarrow B$ induces a long exact sequence in the homotopy groups; namely,
$$\pi_n(F) \rightarrow \pi_n(E) \rightarrow \pi_n(B) \rightarrow \pi_{n-1}(F)\rightarrow \cdots \pi_1(B) \rightarrow \pi_0(F) \rightarrow \pi_0(E) \rightarrow \pi_0(B).$$
My concern is, what does exactly mean being exact at the level of the $0$-th Homotopy groups? In general these are not groups. In particular, is there a geometric interpretation of the connecting map $\pi_1(B) \rightarrow \pi_0(F)$?