Misha’s answer is the best approach to this problem, but finding the eigenvalues of the full $6\times6$ transition matrix is actually very easy because of its special structure.
Observe that we can write the transition matrix as $M=\frac15(\mathbb1_6-I_6)$, where $\mathbb 1_6$ is the $6\times6$ matrix consisting entirely of $1$s. So, if $\mathbf v$ is an eigenvector of $\mathbb1_6$ with eigenvalue $\lambda$, then $M\mathbf v=\frac15(\mathbb1_6\mathbf v-\mathbf v)=\frac15(\lambda-1)\mathbf v$, which means that $\frac15(\lambda-1)$ is an eigenvalue of $M$. The rank of $\mathbb1_6$ is obviously one, so $0$ is an eigenvalue with multiplicity 5, and the other eigenvalue is $\operatorname{tr}\mathbb1_6=6$. Therefore, the eigenvalues of $M$ are $1$ and $-\frac15$.
Of course, we already knew that one of the eigenvalues of $M$ is $1$ with right eigenvector $(1,1,1,1,1,1)^T$ because it’s row-stochastic, and that’s the only eigenvalue we care about for computing the steady-state distribution. The corresponding left eigenvector can be found by computing the kernel of $M^T-I$ or by observing that by symmetry, its left and right eigenvectors are transposes, therefore a left eigenvector of $1$ is $(1,1,1,1,1,1)$, which after normalizing it so that its entries sum to unity gives the result you expected. Computing the $n+1$ step probabilities is a bit messy, but again, because $M$ is symmetric, the eigenspace of $-\frac15$ is the orthogonal complement of the span of this vector, so it’s pretty easy to diagonalize the matrix. You might also observe that if you subtract any two columns from each other, you get a vector with $\pm\frac15$ in the elements corresponding to the column numbers and zero everywhere else, so vectors with a single $1$ and $-1$ are all eigenvectors of $-\frac15$. It’s not hard to come up with an eigenbasis once you’ve noticed this.