If $1=0$, then $a=a\cdot 1=a\cdot 0=0$, i.e. every element is the zero element, which means that the ring is the zero ring. About why $a.0=0$, just note that $a\cdot 0=a\cdot (0+0)=a\cdot 0+a\cdot 0$, so $a\cdot 0=0$.
Actually the fact that $1\neq 0$ comes from the definition of integral domain. As Wikipedia says, "an integral domain is a nonzero commutative ring in which the product of any two nonzero elements is nonzero".
So since every field is an integral domain (*), then every field is in particular a nonzero commutative ring, in other words, in a field we must have $1\neq 0$.
About (*) we can prove it in the following way. Call our field $F$, we only need to show that $F$ doesn't have any non zero divisors of zero. Let's suppose that there is some divisor of zero $a$, then exits $b\in F$ such that $a\cdot b=0$. Now because we are in a field $b$ has an inverse $b^{-1}$, then multiplying by $b^{-1}$ we get $$(a\cdot b)\cdot b^{-1}=a\cdot (b\cdot b^{-1})=a\cdot 1=a=0\cdot b^{-1}=0.$$
Therefore $a=0$ and hence $F$ is an integral domain.
New edit: As a matter of fact, again by Wikipedia we have that a field "is a nonzero commutative division ring". So again, we have by definition that $1\neq 0$. The conclusion is that you don't have to prove that $1\neq 0$ in a field. It's just part of the definition of a field.