It is reasonably clear that the required expectation exists. Let us call it $a$. Let $b$ be the expected number of additional rolls we need, given that we have not yet met our goal, but have just tossed a $6$.
If the first roll is not a $6$, then we have used $1$ roll, and our conditional expectation, given this happened, is $1+a$. If the first roll is a $6$, then we have used a roll, and the conditional expectation is $1+b$. It follows that
$$a=\frac{5}{6}(1+a)+\frac{1}{6}(1+b).\tag{1}$$
Suppose now that we have just rolled a $6$, and have not yet met our goal. With probability $\frac{1}{6}$, we roll a $6$. We have used $1$ roll, and the game is over. With probability $\frac{5}{6}$, we roll a non-$6$, we have used $1$ toss, and the conditional expectation is $1+a$. It follows that
$$b=\frac{1}{6}(1)+\frac{5}{6}(1+a).\tag{2}$$
We have obtained two linear equations in the two unknowns $a$ and $b$. Solve for $a$.
Remark: We have shown how to compute the expectation, and not really answered the question about the probability that $X=i$. For finding the expectation, the probability distribution of $X$ is not the most efficient method. However, it is an interesting problem in itself.
The key calculation that needs to be made is the probability that a sequence of length $n$ ends in a non-$6$, and does not have $2$ consecutive $6$'s. One can get a linear recurrence with constant coefficients for the number of "good" sequences of length $n$, and solve the recurrence in any one of the usual ways.