$\newcommand{\ZpZ}{\mathbb{Z} / p \mathbb{Z}}$
$\newcommand{\ZnZ}{\mathbb{Z} / n \mathbb{Z}}$
I think the statement in the question is true.
Proposition. Let $X, X_1, \cdots, X_n$ be i.i.d random variables that take value $\ZnZ$. Then the probability that $X_1 + \cdots + X_n$ is congruent to $0$ modulo $n$ is at least $2^{-n+1}$.
Since the approaches are mostly orthogonal, I'll write two answers. The first answer proves the statement when $n$ is prime, and the second answer uses the first answer to prove the statement for all $n$.
In this answer, we consider the case where $n = p$ be a prime. The general idea is to decompose the random variables and reduce the problem to a "two-point inequality" (Lemma 2).
Lemma 1. If $a_1, \cdots, a_{p - 1}$ are members of $ \ZpZ$ that are non-zero modulo $p$ and $a$ is any element of $\ZpZ$, then there exists some $S \subset \{1,2,\cdots, p - 1\}$ such that $\sum_{i \in S} a_i$ is congruent to $a$ modulo $p$.
Proof: Let $S_i$ be the set of elements in $\ZpZ$ that can be represented as a subset sum of $a_1, \cdots, a_k$. Then $S_{i + 1} = S_i + \{0, a_{i + 1}\}$. By the Cauchy-Davenport inequality, $|S_{i + 1}| \geq \min(|S_i| + 1, p)$. As $|S_0| = 2$, we have $|S_{p - 1}| = p$ as desired. QED.
From Lemma 1, we can easily obtain
Lemma 2. Let $X_1, \cdots, X_p$ be independent random variables that take two distinct values in $\ZpZ$ with equal probability. Then for any $a$, the probability that $X_1 + \cdots + X_p$ is congruent to $a$ modulo $p$ is at least $2^{-p+1}$.
Proof: By Lemma 1, there are at least two distinct realizations of $(X_1, \cdots, X_p)$ such that $X_1 + \cdots + X_p$ is congruent to $a$ modulo $p$, and each realization happens with probability equal to $2^{-p}$. QED.
The idea now is to decompose the random variables and reduce to the scenario in Lemma 2.
Lemma 3. Let $X$ be a random variable taking value in a finite set $S$, such that $\mathbb{P}(X = a) \leq 1/2$ for any $a \in S$. Then there exists an integer-valued random variable $Z$, and $S$-valued random variables $Y_1, Y_2, \cdots$ independent of $Z$ and each taking two distinct values in $S$ with equal probability, such that $X$ is equi-distributed as $Y_Z$.
Proof: This follows from the following fact: The convex hull of vectors in $\{0, 1\}^k$ with exactly two coordinates equal to $1$ is equal to
$$\{(p_1, \cdots, p_k) \in \mathbb{R}_{\geq 0}^k: p_i \leq \frac{1}{2}(p_1 + \cdots + p_k), \forall i\}.$$
One can prove this fact by assuming the contrary and trying to find a separating hyperplane. QED.
Lemma 4. Let $X, X_1, \cdots, X_p$ be i.i.d random variables that take value $\ZpZ$, such that $\mathbb{P}(X_i = a) \leq 1/2$ for any $a \in \ZpZ$. Then for any $a \in \ZpZ$, the probability that $X_1 + \cdots + X_p$ is congruent to $a$ modulo $p$ is at least $2^{-p+1}$.
Proof: Take $Y_i$ and $Z$ as in Lemma 3, and let $Y^j_{i}$ and $Z^j$ be independent copies of $Y_i$ and $Z$. Then the sum $X_1 + \cdots + X_p$ is equi-distributed as
$$Y^1_{Z^1} + \cdots + Y^p_{Z^p}.$$
Conditioned on any realization of $(Z^1, \cdots, Z^p)$, Lemma 2 tells us that $Y^1_{Z^1} + \cdots + Y^p_{Z^p}$ is congruent to $a$ modulo $p$ with probability at least $2^{-p+1}$. So $Y^1_{Z^1} + \cdots + Y^p_{Z^p}$ is congruent to $a$ modulo $p$ with probability at least $2^{-p+1}$. QED.
This deals with the case where $\mathbb{P}(X_i = a) \leq 1/2$ for any $a \in \ZpZ$. Now let's deal with the other case! The idea is similar: we reduce to a two-point inequality. We say a variable on $\ZpZ$ is close to zero if it assumes at most two distinct values, and assumes value $0$ with probability at least $\frac{1}{2}$
Lemma 5. Let $X_1, \cdots, X_p$ be independent random variables that are close to zero. Then the probability that $X_1 + \cdots + X_p$ is congruent to $0$ modulo $p$ is at least $2^{-p+1}$.
Proof: Let $q_i = \mathbb{P}(X_i = 0)$. If one variable is always zero, say $X_1 \equiv 0$, then
$$\mathbb{P}(X_1 + \cdots + X_p = 0) \geq \prod_{i = 1}^p \mathbb{P}(X_i = 0 ) \geq 1 \cdot (1/2) \cdots (1/2) \cdots (1/2) = 2^{-p+1}.$$
Otherwise, by Lemma 1, there are at least two distinct realizations of $(X_1, \cdots, X_p)$ such that $X_1 + \cdots + X_p$ is congruent to $0$ modulo $p$. One of them is the all zero realization, which happens with probability $q_1 \cdots q_p$. The other realization must happen with probability at least
$$(1 - q_1) \cdots (1 - q_p).$$
Thus, the probability that $X_1 + \cdots + X_p$ is congruent to $0$ modulo $p$ is at least
$$q_1 \cdots q_p + (1 - q_1) \cdots (1 - q_p) \geq 2^{-p+1}.$$
Lemma 6: Let $X$ be a random variable taking value in a finite set $\ZpZ$, such that $\mathbb{P}(X = 0) \geq 1/2$. Then there exists an integer-valued random variable $Z$, and $\ZpZ$-valued random variables $Y_1, Y_2, \cdots$ independent of $Z$ each close to zero, such that $X$ is equidistributed as $Y_Z$.
Proof: Let $q_i = \mathbb{P}(X = i)$. For $1 \leq i \leq p - 1$, let $Z$ take value $i$ with probability $q_i / (1 - q_0)$, and let $Y_i$ take value $0, i$ with probability $q_0, (1 - q_0)$ respectively. QED.
Lemma 7. Let $X, X_1, \cdots, X_p$ be i.i.d random variables that take value $\ZpZ$, such that $\mathbb{P}(X_i = a) \geq 1/2$ for some $a \in \ZpZ$. Then the probability that $X_1 + \cdots + X_p$ is congruent to $0$ modulo $p$ is at least $2^{-p+1}$.
Proof: Without loss of generality, assume $a = 0$. Take $Y_i$ and $Z$ as in Lemma 6, and let $Y^j_{i}$ and $Z^j$ be independent copies of $Y_i$ and $Z$. Then the sum $X_1 + \cdots + X_p$ is equi-distributed as
$$Y^1_{Z^1} + \cdots + Y^p_{Z^p}.$$
Conditioned on any realization of $(Z^1, \cdots, Z^p)$, Lemma 5 tells us that $Y^1_{Z^1} + \cdots + Y^p_{Z^p}$ is congruent to $0$ modulo $p$ with probability at least $2^{-p+1}$. So $Y^1_{Z^1} + \cdots + Y^p_{Z^p}$ is congruent to $0$ modulo $p$ with probability at least $2^{-p+1}$. QED.
Combining Lemma 4 and Lemma 7, we obtain the desired result.
Proposition. Let $p$ be a prime. Let $X, X_1, \cdots, X_p$ be i.i.d random variables that take value $\ZpZ$. Then the probability that $X_1 + \cdots + X_p$ is congruent to $0$ modulo $p$ is at least $2^{-p+1}$.