Let $X$ be a locally-compact, Hausdorff space, and let $\mathcal{A}:=C_{0}(X)$ the $C^{*}$-algebra of complex-valued, continuous functions vanishing at infinity. Let $\mathcal{B}:=M_{n}(\mathbb{C})$ the $C^{*}$-algebra of $n\times n$ complex matrices. The tensor product $\mathcal{A}\otimes\mathcal{B}$ is well-defined as a $C^{*}$-algebra and it is isomorphic to $C_{0}(X,\mathcal{B})$ (see for instance thm: II.9.4.4 in Blackadar's book).
Since the dual space $\mathcal{A}'$ of $\mathcal{A}$ may be identified with the space of complex-valued Radon measures on $X$, and the dual space $\mathcal{B}'$ may be identified with $\mathcal{B}$ itself, I was wondering if it is possible to identify the dual space $(\mathcal{A}\otimes\mathcal{B})'\cong(C_{0}(X,\mathcal{B}))'$ with the space of $\mathcal{B}$-valued Radon measures on $X$, and thus the space of states of $\mathcal{A}\otimes \mathcal{B}$ with the space of $S$-valued Radon measures on $X$, where $S$ is the space of positive semidefinite matrices with unit trace.
Since it is just a mere curiosity triggered by a casual conversation I had yesterday, I did not yet really try to prove anything, but I have the impression that this could be a well-known result for experts in $C^{*}$-algebra theory.