If$$\tan \alpha = 1, \text{ }\tan \beta = {3\over 2}, \text{ }\tan \gamma = 2,$$then does it follow that $\alpha$, $\beta$, $\gamma$ are linearly independent over $\mathbb{Q}$?
It is possible to test combinations $m\alpha+n\beta+\ell\gamma$ with some small integer coefficients $m,n,\ell$. The tool for doing that is the sum formula for tangents of two angles with known tangents: $$ \tan(x\pm y)=\frac{\tan x\pm\tan y}{1\mp\tan x\tan y}. $$ For example, judging from a picture $\beta+2\gamma$ is relatively close to $\pi=4\alpha$, but the calculations: $$ \tan 2\gamma=\frac{2+2}{1-2\cdot2}=-\frac43, $$ $$ \tan(\beta+2\gamma)=\frac{3/2-4/3}{1+(3/2)(4/3)}=\frac1{18} $$ show that it is not a match.