The reference text for this question is: Pedersen, Analysis Now, GTM 118.
The $\sigma$-weak topology on $B(H)$ (the bounded linear operators on a Hilbert space $H$) is the weak$^*$-topology on $B(H)$ seen as the dual of the Banach algebra $B_1(H)$ ($T\in B_1(H)$ if $T$ is a compact operator such that its norm in $B_1(H)$ is $tr(|T|)<\infty$ - see Pedersen 4.6.10, 3.4.6, 3.4.12, 3.4.13).
The weak operator topology on $B(H)$ is the one generated by the semi norms $|(Tx,y)|$ as $x,y$ range in $H$ and $(\cdot,\cdot)$ is the inner product on $H$ - see Pedersen 4.6.1.
It is shown in Proposition 4.6.14 that the weak operator topology and the $\sigma$-weak topology overlap on the ball $B(H,n)$ of operators $T\in B(H)$ of norm at most $n$.
This gives that any $\sigma$-weakly continuous functional $\phi$ when restricted to $B(H,1)$ is continuous with respect to the weak operator topology.
Now propositions 4.6.11 and 4.6.4 give the following characterizations of continuous functionals in these topologies:
4.6.11: a functional $\phi:B(H)\to\mathbb{C}$ is $\sigma$-weakly continuous if and only if there exists sequences $(x_n)_{n\in\mathbb{N}}$ and $(y_n)_{n\in\mathbb{N}}$ of elements of $H$ such that $\sum_{n\in\mathbb{N}}||x_n||+\sum_{n\in\mathbb{N}}||y_n||<\infty$ and $\phi(S)=\sum_{n\in\mathbb{N}}(S(x_n),y_n)$.
4.6.4: a functional $\phi:B(H)\to\mathbb{C}$ is continuous with respect to the weak operator topology if and only if there exists sequences $(x_0,\dots, x_n)$ and $(y_0,\dots,y_n)$ of elements of $H$ such that $\phi(S)=\sum_{j=0,\dots, n}(S(x_j),y_j)$.
I can follow the proof of proposition 4.6.14, but I don't understand how this translates at the level of these different characterizations, i.e.:
Assume $\phi(S)=\sum_{n\in\mathbb{N}}(S(x_n),y_n)$ is $\sigma$-weakly continuous, what are the vectors $(z_0,\dots, z_n)$ and $(w_0,\dots,w_n)$ such that $\phi(S)=\sum_{i\leq n}(S(z_i),w_i)$ for all operators $S$ of norm at most 1?
How can it happen that a $\sigma$-weak continuous $\phi$ functional is such that $\phi\restriction B(H,n)=\psi_n$ with $\psi_n$ continuos for the weak operator topology but for all $n$ $\phi\neq\psi_n$?
Some examples would be illuminating.
Thanks in advance